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恭喜刘杰博后,魏永亮博士的研究成果被Journal of the American Chemical Society接收!

Jun 13, 2018



Cobalt-Catalyzed Trifluoromethoxylation of Epoxides
https://pubs.acs.org.ccindex.cn/doi/abs/10.1021/jacs.8b10298
 
Abstract: A catalytic ring-opening reaction of epoxides by nucleophilic trifluoromethoxylation of trifluoromethyl arylsulfonate has been developed based on the use of a cobalt catalyst. This reaction provides an efficient, simple route for directly construction of a wide range of vicinal trifluoromethoxyhydrins under mild conditions. In addition, this method can convert terminal epoxides into target products with good chemo- and regioselectivity.